Abstract
One new Cd-based Metal-Organic Framework (MOF), {[Cd(cpnc)(H2O)]}n (1), has been synthesized and characterized based on a bidentate carboxylate ligand, H2cpnc, (H2cpnc = (6-(4-carboxyphenyl) nicotinic acid). The Cd cations were connected by cpnc2− ligands to form a rare 6-c rob 3D network. In addition, the effects of different organic reagents and ions on the fluorescence properties of the compound 1 have been studied. The luminescence titration experiments show that a significant quenching of fluorescence intensity can be observed after addition of Fe3+ and K2Cr2O7.
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