Abstract
ESR has been used to study H-atom abstraction by ĊH 2CO − 2 radicals from methylene groups of matrix molecules in α-glycine single crystals of compound isotopic composition. D → H substitution at the reaction site does not affect the kinetics, while deuteration of the amino group changes not only the rate but also the kinetic law. The results obtained have been interpreted on the assumption that the reaction rate depends on the structure and molecular dynamics of the cage with the reagents, rather than on the atom transfer.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
