On the existence of the thermodynamic limit for classical systems with nonspherical potentials

Abstract

It is shown, that the configurational partition function for a classical system of molecules interacting with nonspherical pair potential is proportionals to the configurational partition function for a system of particles interacting with temperature-dependent spherical k-body potentials (k ⩾2). Therefore, the thermodynamic limit for nonspherical molecules exists if the effective k-body interaction is stable and tempered. A number of criteria for the nonspherical potential are developed which ensure these properties. In case the nonsphericity is small in a certain sense, stability and temperedness of the angle-averaged nonspherical potential are sufficient to ensure thermodynamic behaviour.