Abstract

I argue that the claim made by Scerri that in many-electron atoms, orbitals do not exist according to quantum mechanics, is incorrect, for it relies on the view that orbitals are entities. Orbitals are states, not entities, and their use in describing many-electron atoms should be seen as an approximation. The writings by Scerri and others on the issue of realism that are based on the claim therefore lead astray. I furthermore disentangle two issues that Scerri discusses in arguing for his claim: that of electron correlation and that of the Pauli principle. Finally, I point out that more generally there is a misconception in chemistry of what quantum states are.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.