Omphacitite formation and fluid-rock interaction processes in an intra-slab eclogite-facies shear zone

Abstract

We document the formation of omphacitites in the Monviso Lago Superiore Unit (W. Alps) where eclogite-facies, serpentinite-bearing shear zones host ample evidence for intense intra-slab fluid flow. In the first locality studied, a serpentinite-hosted jadeitite block is rimmed by strained omphacitite (with lawsonite pseudomorphs and minor phengite). U-Th-Pb zircon dating yields a protolith age of c.150 Ma, thus pointing to a burial-related replacement of a former Tethyan seafloor material, and revealed a lack of alpine rims. Multi-mineral Rb-Sr dating of the minerals forming this omphacitite rind yields an isochron age of 41.6 ± 0.7 Ma, corresponding to the early exhumation path still within the eclogite-facies. In this case, omphacitization led to the nearly complete replacement of the former prograde jadeitite through solution-precipitation and was followed by crystal-plastic deformation processes.In various Monviso localities, Fe-Ti metagabbro blocks (commonly exhibiting brecciated garnetite fragments) display evidence for intense fluid-rock interactions leading to the formation of decimeter-thick, weakly strained omphacite-dominated rinds (with minor amounts of lawsonite, clinochlore and talc) around the blocks at the contact with the surrounding serpentinite. Partly dissolved zircon crystals separated from omphacitite rimming an eclogitic Fe-Ti metagabbro block only yielded middle-Jurassic protolith ages. This indicates that omphacitite rinds did not overgrow the eclogite blocks but rather replaced metasomatically the garnet-rich eclogitic assemblage. The omphacitization overprint occurred independently of the nature of the protolith (namely, forming after a jadeitite or after an Fe-Ti eclogite) as a consequence of infiltration of externally-derived fluids and subsequent element sequestration from the incoming fluid phase. These observations highlight the extraordinary ability of eclogite-facies metasomatic fluids to nearly totally overprint rocks as resistant and impermeable as Monviso eclogite breccias or jadeitites.