Abstract
A kinetic study of the reaction of [Pt(ol)Cl3]- (ol=allylNH3=, allylPEt3=, allylSO3, pent-4-enylNH3= with bipyridyl (Bipy) in acidic 95 percent aqueous methanol to give cis-[Pt(Bipy)Cl2] is reported. The rate law takes the form 1/kobs=k(Cl-)/(Bipy), where kobs is the pseudo-first-order rate constant. The proposed mechanism involves slow formation of the solvato species [Pt(ol)(S)Cl2] followed by slow reaction with Bipy to give the final product with replacement of the coordinated olefin.
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