Abstract

In this study, polyamide (PA) thin film composite (TFC) reverse osmosis (RO) membrane filtration was used in edible oil wastewater emulsion treatment. The PA-TFC membrane was characterized using mechanical, thermal, chemical, and physical tests. Surface morphology and cross-sections of TFCs were characterized using SEM. The effects of edible oil concentrations, average droplets size, and contact angle on separation efficiency and flux were studied in detail. Purification performance was enhanced using activated carbon as a pre-treatment unit. The performance of the RO unit was assessed by chemical oxygen demand (COD) removal and permeate flux. Oil concentration in wastewater varied between 3000 mg/L and 6000 mg/L. Oily wastewater showed a higher contact angle (62.9°) than de-ionized water (33°). Experimental results showed that the presence of activated carbon increases the permeation COD removal from 94% to 99%. The RO membrane filtration coupled with an activated carbon unit of oily wastewater is a convenient hybrid technique for removal of high-concentration edible oil wastewater emulsion up to 99%. Using activated carbon as an adsorption pre-treatment unit improved the permeate flux from 34 L/m2hr to 75 L/m2hr.

Highlights

  • The increased need for edible oil all over the world has resulted in the development of many edible oil plants, leading to the disposal of huge amounts of wastewater

  • Wastewater from vegetable edible oil industries contains a higher fraction of slowly biodegradable contents, causing noteworthy environmental issues such as ground and surface water pollution

  • The Scanning Electron Microscopy (SEM) images of the thin film composite (TFC) membrane were investigated before and after oily the TFC were taken after the cutting with freeze-fracturing

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Summary

Introduction

The increased need for edible oil all over the world has resulted in the development of many edible oil plants, leading to the disposal of huge amounts of wastewater. Olive, soybean, cottonseed, and sunflower are considered the main sources for extracting edible oil [1]. Persistent market research (PMR) has reported that the global oil market value is predicted to increase to 130.3 billion US$ by 2024, recording a compound annual growth rate of 5.1%. Treatment of edible oil industry effluents is considered a major environmental issue. Disposal of untreated oily wastewater effluents can result in pollution of soil, water, and air. Wastewater from vegetable edible oil industries contains a higher fraction of slowly biodegradable contents, causing noteworthy environmental issues such as ground and surface water pollution. Odor nuisance, water color, and low soil quality can be addressed and reported, taking into consideration environmental issues and human health. It is necessary to treat oily wastewater effluents to meet environmental regulations and standards

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