Occurrence of nutrient and contaminant elements in biomass ashes and their significance for potential soil fertilization

In a relationship between the grain yields and concentrations of a nutrient element at a well defined stage of development under varying growing conditions, i.e. 2.0 g Dry Matter weight (DMw) per hill, the boundary line concept dictates that the grain yield corresponding to the points along the boundary of data points is predominantly determined by the varying concentrations of the respective nutrient element. These concentrations, defined as “Pure‐effect Concentrations,”; form the bases to develop the pure‐effect yield curves. Pure‐effect yield curves were developed for N, P, K, Ca, Mg and Na. The absolutely optimal concentrations or absolute reference values, i.e. the concentrations of various nutrient elements at 2.0 g DMw level corresponding to maximum grain yield, were found to be 3.3% N, 0.36% P, 3.9% K, 1.3% Ca, 0.25% Mg and 0.03% Na. The relationships were developed between the concentrations of other nutrient elements corresponding to pure‐effect concentrations of a nutrient element in question in all combinations by treating each nutrient element as pure‐effect nutrient at a time. These relationships enable one to determine the varying optimal concentrations of other nutrient elements corresponding to the concentrations of the pure‐effect nutrient. These concentrations are defined as “Relatively Optimal Concentrations”; or “Relative Reference Values.”; The absolute and relative reference values are the bases for developing the diagnosis and yield prognosis models which can be used to evaluate the nutritional status of lowland rice plants and to predict the grain yield based on the elemental composition of plants at 2.0 g DMw per hill. The procedure for the application of diagnosis and yield prognosis models is demonstrated. A very good agreement was found between the grain yield predicted by using these models and the actual yields, thus indicating a high degree of accuracy in predicting the grain yield.

Foraging for edible and medicinal mushrooms is a cultural and social practice both globally and in the United States. Determining the toxic and nutrient element concentrations of edible and medicinal mushrooms is needed to ensure the safe consumption of this food source. Our research examined wild, foraged mushrooms in New England, USA to assess nutrient (Ca, K, Mg, P) and toxic (As, Hg, Pb, Cd) element relationships between mushrooms, substrates, and soils. We examined a gradient in nutrient and toxic elements from more rural Mountain and Hill Zones in Massachusetts, Vermont, and New Hampshire to more developed and urban Valley and Coastal Zones in Connecticut. Substrates and mineral soils were moderate to weak predictors of mushroom tissue concentrations. We found significant differences in nutrient and toxic element concentration among the five common genera: Ganoderma, Megacollybia, Pluteus, Pleurotus, and Russula. In particular, Pluteus had consistently higher toxic element concentrations while Pleurotus and Russula had the highest Bioaccumulation Factors (BAFs). We found that the urban areas of the Valley and Coastal zones of Connecticut had Cd Target Hazard Quotient (THQ) values and ΣTHQ values > 1.0, indicating potential non-carcinogenic health hazard. However, the trend was largely driven by the > 2.0 Cd THQ for Pluteus. Our results suggest that foraging in more urban areas can still yield mushrooms with safe concentrations of toxic elements and abundant nutrients. Further research of this kind needs to be conducted within this region and globally to ensure humans are consuming safe, foraged mushrooms.

We studied the nutrient cycle of a planted forest of Pinus tabulaeformis in the Miyun Reservoir Watershed, Beijing. Results show that the total biomass of P. tabulaeformis stands at age 29 in the experimental area is 92627 kg/hm2, and the total nutrient store is 695.17 kg/hm2 including nitrogen (N), phosphorus (P), kalium (K), calium (Ca) and magnesium (Mg). The sequence of their contents in different organs was given as follows: needle>branch> trunk>root. The annual amount of 85.37 kg/hm2 of five nutrient elements were assimilated by P. tabulaeformis, about 0.34% of the total store in soil, and 3.30% of available nutrient store in soil depth from 0 to 30 cm. The nutrient annual retention is 35.92 kg/hm2, annual returning 49.46 kg/hm2, the rain input 26.04 kg/hm2 to the five nutrient elements. The parameter absorption coefficient, utilization coefficient, cycle coefficient and turnover period were cited to describe the nutrient elements cycle characteristic of the planted forest ecosystem of P. tabulaeformis. The absorption coefficient is the ratio of plant nutrient element content to soil nutrient element content, and its sequence of five nutrient elements was given as follows: N>P>K>Ca>Mg. Utilization coefficient is the ratio of the nutrient element annual uptake amount to the nutrient element storage in standing crops, and its sequence of five nutrient elements was: Mg>K> P>N>Ca. The big utilization coefficient means more nutrients stored in the plant. The cycle coefficient is the ratio of the nutrient element annual return amount to the nutrient element annual uptake amount, its sequence: Ca>N>P>K>Mg. Turnover period is the ratio of the nutrient storage in the crops to the annual returning, its sequence: Mg>K>P>N>Ca.

Toxic Hg species pose a global ecological threat due to the significant anthropogenic emissions of Hg to the atmosphere, particularly during coal combustion. An investigation about the content, association and modes of occurrence of Hg in diverse biomass ash (BA) varieties and its behaviour during biomass combustion was performed. These BAs belonging to woody, herbaceous, agricultural and aquatic biomass groups were examined with different chemical and mineralogical methods, as well as thermal and leaching procedures. The Hg contents in BAs are low and vary between 0.0032 and 0.0452 ppm (mean 0.0225 ppm). About 60–99% (mean 87%) and 63–100% (mean 91%) of Hg in biomass were volatilized at 500 °C and 700 °C, respectively, and only limited amounts of Hg were captured by BAs enriched mostly in salts such as carbonates, oxyhydroxides, phosphates, sulphates, and chlorides. The affinity of residual Hg in the BA system is towards relatively stable Fe-, P-, Ti- Al-, K-, and Si-bearing minerals (especially K aluminosilicates and Fe oxides), as well as less stable chlorides (particularly sylvite). The potential mode of Hg occurrence in BA is likely in the form of impurities in the above minerals. Alternative renewable fuels poor in Hg such as appropriate sustainable biomasses (0.001–0.043 ppm Hg) are suggested to partially or completely substitute the industrial coals enriched in Hg (0.14–0.57 ppm) and used in Bulgarian thermoelectric power plants and thus minimize the ecological problems related to this element.

Comparative analyses were conducted on the nutrient element content and returning amount of main fractional compositions of litter in Korean pine (KP), Mongolian Scots pine (MSP) and Dahurian larch (DL) plantations in Laoshan Plantation Experiment Station of Maoershan Experiment Forest Farm of Northeast Forestry University. The results are as follows: (1) The nutrient element content and returning amount in litter varies among different fractional compositions and tree species, the total returning amount of all nutrient elements and the returning amount of K, Ca, Mg, N and P are DL > MSP > KP, the returning amount of Cu is DL > KP > MSP, the returning amount of Fe and Mn are MSP > DL > KP; (2) To KP and DL plantations, the main nutrient element returned is dead needles; dead branches, bark scales and dead cones account for a little proportion; whereas to MSP plantation, besides dead needles, dead branches and bark scales also play an important role in the return of nutrient elements; (3) A little deal of dead leaves can provided a great deal of returning amount of nutrient elements.

The quantity of plant nutrient elements removed from soil by wheat (Triticum aestivum) seedlings were compared with the results of soil tests. Four soils were selected to represent the major parent material and climatic factors responsible for the formation of important agricultural soils in the central eastern Cape Province of South Africa. Acid‐washed sand was used as control. Seedlings were grown for 21 days and nutrient element content in both plant material and soil were determined. Soils derived from dolerite rocks had significantly (P<0.05) higher calcium (Ca), magnesium (Mg), potassium (K), sodium (Na), and phosphorus (P) than those derived from sedimentary rocks. However, iron (Fe), manganese (Mn), and copper (Cu) were higher in soils derived from sedimentary rocks compared to those from dolerite rocks. The differences are attributed to elemental composition of minerals in the two parent rock materials. Within each rock group, soils derived from sites with higher temperature and low rainfall (semi‐arid climate) had significantly (p<0.05) higher nutrient element content than those from sites with lower temperatures and higher rainfall (humid climate). As far as plant growth is concerned, all the soils were well supplied with Ca, Mg, K, Na, and zinc (Zn), but were deficient in P, Fe, and Mn. The trend in uptake of soil nutrient elements by wheat seedlings mirrored their concentration in the soils. Estimates of plant‐available nutrient elements as determined by soil tests and their uptake as determined by tissue concentration were highly correlated for some nutrient elements (r2=0.83, 0.79, 0.94, 0.54, 0.69, and 0.61 for Ca, Mg, K, P, Na, and Zn, respectively) and weak for others (r2=0.47, 0.35, and 0.37 for Fe, Mn, and Cu, respectively). Notwithstanding the shortcomings of extrapolating pot derived results to field conditions, it is concluded that the Neubauer technique may offer a rapid and relatively inexpensive way of relating extractable nutrient elements with plant uptake and growth. Further in country correlation studies are, however, recommended.

Supplementation strategies and nutritional management of ewes during critical production periods of breeding and gestation is an important consideration, particularly when ewes are on winter range. Clinical and subclinical trace mineral deficiencies at these times limit ewe productivity in these extensive environments. The objectives of this study were to (1) quantify mineral element concentrations of common forages on winter range, and (2) evaluate producer supplementation strategies using a survey. We hypothesized that mineral element concentrations in winter forages were inadequate to meet ewe requirements during critical production stages and shrub species would contain higher levels of macro- and micro-mineral element concentrations than grass species. Forage samples were collected from 25 ranches across Wyoming winter range and were compiled by species and analyzed for nutrient and mineral element composition; however, data presented herein represents the first year of data collection (12 of 25 ranches). Nutrient and mineral element concentration results indicated an effect in CP, Ca, P, K, Mg, S, Na, Zn, Cu, Se, Mn, and Mo concentrations between grass and shrub species (P &amp;lt; 0.05). Specifically, Mg and Mo concentrations were higher in grasses while the other mineral element concentrations were higher in shrubs. No effect was observed for Fe and Co concentrations between grass and shrub species (P = 0.37 and P = 0.29). Survey results revealed that 80% of ranches had more than 1000 sheep, and 47% of respondents utilized winter range for 131 to 170 day periods throughout production year. While on winter range the majority of producers (47%) supplement with a protein source. Additionally, 58% do not supplement white salt, while 47% supplement a complete trace mineral mix.

Thermal behaviour of biomass ashes in air and inert atmosphere with respect to their decarbonation

Jerusalem artichokes store carbon (C) predominately in the form of inulin, a functional food of increasing interest due to its dietary health benefits for humans and calorie replacement potential in processed foods. To better understand the developmental and agronomic requirements of this crop, the allocation of C and nutrient elements into individual plant parts (stems, leaves, stolons, tubers, ‘seed’ tuber, and roots) was monitored at 2‐week intervals throughout the entire growth cycle of the cultivar ‘Sunchoke’ grown on a Cecil sandy clay loam. Accumulation patterns of C and nutrient elements in individual plant parts were generally in accordance to the pattern of dry matter accumulation, though concentration patterns differed. Overall, nutrient element levels in vegetative structures decreased with the onset of rapid tuber development. Leaves had the highest nutrient levels, except iron (Fe) and sodium (Na). The concentrations of nitrogen (N), phosphorus (P), potassium (K), sulfur (S), and copper (Cu) in tubers were greater than in stems. Total N, P, and K concentrations in the stolons were at lower levels and the total calcium (Ca), Fe, and manganese (Mn) at higher levels compared to the tubers. During rapid tuber growth, the concentration of individual phloem‐mobile nutrient elements (e.g., N, P, and K) in the leaves and stems decreased progressively due in part to reallocation. In contrast, the concentration of less mobile nutrient elements (e.g., Ca and Mn) in the leaves and stems generally increased due to losses of C and other mobile materials. In the tubers, the concentration of C and most nutrient elements remained fairly constant through the final harvest, indicating carbohydrates and nutrient elements were accumulating at the same rate. Knowledge of C and nutrient element allocation/ reallocation in the Jerusalem artichoke is of value for improving fertilization strategies and in identifying critical traits for the selection of new, high yielding cultivars.

喀斯特峰丛洼地不同类型森林养分循环特征

Through the content analysis of nutrient elements in the soil and in the needle at the different site classes and periods of growth ofP. koraiensis, and in a single growing season, some conclusions can be drawn below: Most of the soil nutrient elements were higher at the good sites than at the poor ones in an annual average concentration of them, i.e., site class 1 > site class 2> site class 3. And forP. koraiensis tree at every site class, the nutrient elements in their needles did the same. However, each of the elements in the soil or in the need was seldom at the same level of concentration on the good or on the poor site during different periods of growth. There are no an inevitable relationship between the contents of the soil nutrient elements and the needle’s. And whether these elements are high or low within a tree body may depend on the physiogical requirement of the tree, but not on their contents in the environment. Some nutrient elements required forP. koraiensis varied with growth periods during a whole growing season. N, P and K, for example, were greatly needed only at the fast growth period, while Ca at the initial growth period; and on the contrary, Ca was needed less at the fast growth period. In intensive forest management, therefore, fertilizers with N, P and K should much be applied at the fast growth period, while fertilizer with Ca at the initial growth period to meet requirements of growth ofP. koraiensis trees.

Effects of cadmium on uptake and translocation of nutrient elements in different welsh onion (Allium fistulosum L.) cultivars

Mineral carbonation of thermally treated and weathered biomass ashes with respect to their CO2 capture and storage

Characteristics of trace elements and potential environmental risks of the ash from agricultural straw direct combustion biomass power plant

The study explored the post-wildfire elemental composition of parts (wood, bark, branch, cone, trunk, litter, twig, needle, sward, fallow, sapling, etc.) and by-products (biomass ashes, partly burnt parts, and char) of different woody species in the Bohemian Switzerland National Park, Czech Republic, and considered their effects on soils. Multi-elemental analysis of the fire by-products of the woody species was determined with inductively coupled plasma-optical emission spectrometry and mass spectrometry and compared with control biomass samples unaffected by wildfire. Most fire by-products were slightly alkaline, with acidic ashes obtained from blueberry wood. The by-products of the wildfire were characterized by varied total contents of macro (P, Ca, K, Mg, and S), micro (Na, Mn, Fe, Cu, and Zn), and other elements (B, Co, Mo, and V) vital to soil fertility and plant growth. The mean content of macro elements in the biomass ashes was up to 4.16 P, 23.5 Ca, 2.48Mg, 63K, and 5.57 S g kg-1. These values were comparatively lower than published data for ashes obtained under optimized conditions, e.g., those combusted in power generation facilities. Conversely, partly burnt parts-an indication of incomplete combustion-had higher 9.22 P, 79 Ca, and 5.99Mggkg-1 contents in spruce needles than in biomass ashes and the control. Variations in woody species and anthropogenic activities in areas of wildfires produced varied As, Cd, Cr, Ni, and Pb contents above EU fertilizer regulation. Caution in applying biomass ashes from wildfires on fields is required due to risk/toxic elements input from anthropogenic activities. Wildfire effects on the elemental composition of woody species can provide information on plant parts most suitable for biomass ashes for soil and ecosystem safety.