Occurrence of Cyclic and Linear Siloxanes in Indoor Dust from China, and Implications for Human Exposures

Abstract

Siloxanes are used in a wide variety of personal-care and other consumer products. Although there is clearly a potential for contamination of indoor dust with siloxanes, reports of occurrence of siloxanes in indoor dust were not available, prior to the present study. Here, we have determined the concentrations and profiles of four cyclic siloxanes, octamethylcyclotetrasiloxane (D(4)), decamethylcyclopentasiloxane (D(5)), dodecamethylcyclohexasiloxane (D(6)), and tetradecamethylcycloheptasiloxane (D(7)), as well as 11 linear siloxanes, from L(4)-L(14), in 100 dust samples collected in China. Cyclic and linear siloxanes were found in all dust samples, with the linear siloxanes L(9)-L(14) being the predominant compounds. Concentrations of total siloxanes in dust ranged from 21.5 to 21,000 (mean: 1540 +/- 2850) ng g(-1). The highest concentration of the individual linear siloxanes, L(9)-L(14), ranged between 2680 and 6170 ng g(-1). Concentrations of total linear siloxanes (TLS) were 1-2 orders of magnitude higher than concentrations of total cyclic siloxanes (TCS), in all indoor dust samples. Siloxane concentrations in dust were associated with the number of electrical/electronic appliances, number of occupants, and smokers living in the house. Based on the measured siloxane concentrations and on estimated daily ingestion rates of dust by toddlers and adults, we calculated the daily intake of siloxanes. For adults, daily exposure to total siloxanes, based on an average dust intake rate and median exposure concentration, was calculated to be 15.9 ng day(-1); the corresponding value for toddlers was 32.8 ng d(-1).