Abstract
This paper numerically investigates optimizing trapezoidal flow channel cross-sectional shapes to improve all‑vanadium redox flow battery performance. A 3D steady-state multiphysics model coupling fluid dynamics, mass transfer, and electrochemistry was developed in COMSOL. Eight trapezoidal and one rectangular cross-section serpentine flow fields were simulated at varied flow rates. Results showed the TCS-T06 design reduced pressure drop by 12 % and pump power by 12 % versus the RCS. The concentration distribution of VO2+ was also improved, enhancing mass transfer. At 60 mA/cm2, TCS-T06 achieved 0.9 % higher pump power-based voltage efficiency. The optimized trapezoidal cross-section was proven to minimize losses, improve electrolyte distribution, and enhance VRFB performance. This work provides guidance for optimizing trapezoidal flow channel cross-sections to improve VRFB performance via enhanced mass transfer and reduced pressure drop.
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