Abstract
New syntheses were carried out by alternating free radical additions of ethyl, n-propyl, n-butyl, sec-butyl, cyclohexyl, α-chloromethyl, α-chloroethyl, γ-chloropropyl and 5-(methoxycarbonyl) pentyl radicals to pairs of conjugated olefins. The sources of the alkyl radicals were the redox systems: acyl peroxides/cuprous ion and 1-methoxycyclohexylhydroperoxide/ferrous ion. The relative reactivities of the above mentioned radicals towards butadiene, acrylonitrile, 2,3-dimethylbutadiene, methyl acrylate, methyl methacrylate, acrylic acid and maleic anhydride are discussed in quantitative terms according to their nucleophilic character.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
