Novel synthesis and electrophoretic response of low density TiO–TiO 2–carbon black composite

Abstract

Novel low density TiO–TiO 2–carbon black composite was synthesized, which involved the deposition of inorganic coating on the surface of core–shell latex particles and subsequent removal of latex particles by calcination in high-purity nitrogen. The morphology and interior structure were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The images exhibited the composite had spherical shape and smooth surface, and the interior structure was hollow or porous. X-ray diffraction peaks (XRD) were mostly in agreement with the standard diffraction patterns of rutile TiO 2. In addition, the observed peaks at 2 θ of 43.5°, 50.6° and 74.4° can be indexed to (1 1 1), (2 0 0) and (2 2 0) planes of cubic phase TiO. The X-ray photoelectron spectroscopy (XPS) results indicated that composite consisted of carbon black, TiO and TiO 2. The apparent density of the composite was suitable to 1.62 g cm −3, due to density matching with suspending media. Glutin–arabic gum microcapsules containing TiO–TiO 2–carbon black composite electrophoretic liquid were prepared via complex coacervation. The particles in the microcapsules showed excellent electrophoretic mobility under a DC field.