Abstract
An efficient synthetic approach to a novel substituted tetrathieno[2,3- b ]porphyrazine, its Mg, Zn, Lu complexes and a Lu triple-decker complex was developed. Spectral properties and aggregation phenomena of the target compounds were investigated by UV/Vis spectroscopy and atomic force microscopy (AFM). Electrochromic behaviour of the Zn complex was studied by electrochemistry and spectroelectrochemistry. ► Novel highly soluble substituted porphyrazines were synthesised in high yields (45–80%). ► Heterocyclic ring annelated sandwich-type porphyrazine complex was synthesised for the first time. ► Spectral properties and aggregation phenomena of the target compounds were investigated by UV/Vis spectroscopy and AFM. ► Electrochromic behaviour of the Zn complex was studied by electrochemistry and spectroelectrochemistry.
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