Abstract
Analysis of the effects of added benzyl alcohol and a heavy atom (Br −) on the quantum yields for the benzophenone-sensitized reaction of the title hydroxylamine in hexadecyltrimethylammonium chloride micelles revealed that the benzoyloxy-migrated products are derived from the amidyl-benzoyloxyl radical pair that is present at the micellar surface, whereas the amidyl-phenyl radical pair that is penetrated more deeply into the micellar interior is responsible for the appearance of the phenyl-rearranged products.
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