Abstract
Reactions of primary amines with the perfluorovinyl complex [{Fe(CO)3}2{µ-C(SMe)(CF3)CCF2}]1 proceed with cleavage of two C–F bonds to give 2, whereas with secondary amines fluorine migration and C–F bond rupture afford the novel organometallic complex 3; both 2 and 3 have been characterized by X-ray analysis.
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