Abstract
The compounds tert-butylarsenium(III) tri-μ-chlorido-bis[trichloridotitanium(IV)], (C(4)H(12)As)[Ti(2)Cl(9)] or [(t)BuAsH(3)][Ti(2)(μ-Cl)(3)Cl(6)], (II), and bis[bromidotriphenylarsenium(V)] di-μ-bromido-μ-oxido-bis[tribromidotitanium(IV)], (C(18)H(15)AsBr)(2)[Ti(2)Br(8)O] or [Ph(3)AsBr](2)[Ti(2)(μ-O)(μ-Br)(2)Br(6)], (III), were obtained unexpectedly from the reaction of simple arsane ligands with Ti(IV) halides, with (II) lying on a mirror plane in the unit cell of the space group Pbcm. Both compounds contain a completely novel ion, with [(t)BuAsH(3)](+) constituting the first structurally characterized example of a primary arsenium cation. The oxide-bridged titanium-containing [Ti(2)(μ-O)(μ-Br)(2)Br(6)](2-) dianion in (III) is also novel, while the bromidotriphenylarsenium(V) cation is structurally characterized for only the second time.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Acta Crystallographica Section C Crystal Structure Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
