Abstract
Two novel cluster coordination polymers, {[W4O4S12Cu12Cl2(4,4‘-bipy)12]2Cl.4H2O}n (1) and {[(n-Bu)4N]2[W2O2S6Cu6Br4(4,4‘-bipy)3]}n (2) (4,4‘-bipy = 4,4‘-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS3Cu3] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.
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