Abstract

The high production cost and extremely weak mechanical properties of SiO2 aerogels have been two major challenges hindering its widespread application. Atmospheric pressure drying (APD) has always been regarded as the optimal process to reduce costs. However, traditional APD is cumbersome, still uses a large amount of expensive raw materials, and is extremely immature. In this study, a novel APD was developed, inspired by the wing changes during adult damselfly process. Inorganic silica source/water was used as the raw material, and CO2 was used instead of low surface tension solvent to stabilize the aerogel skeleton structure in situ, and ultimately aerogel material was obtained. The thermal conductivity of pure aerogels was as low as 0.0264 W/(m·K), the porosity reached 94.7 %, and the preparation cycle was only 28.5 h. The thermal stability of the skeleton structure and the chemical stability of surface were investigated and showed the hydrophobicity to withstand temperatures up to 400 °C. Aerogel composites feature low thermal conductivity of 0.0283 W/(m·K), and prominent thermal insulation properties over a wide temperature range of 50–300 °C. For traditional APD, this method shortens preparation cycle by 1–6 times. Compared with the commercial aerogel, the cost is reduced by 38.2 %, and the process is simple and environmentally friendly under the premise of ensuring excellent performance.

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