Abstract

The [Ph4Sb]4+[Sb4I16]4− · 2Me2C=O and [Ph4Sb]3+[Sb5I18]3− complexes were synthesized by reacting tetraphenylstibonium salts Ph4SbX (X = I, OSO2C6H4Me-4) with antimony triiodide in acetone. According to X-ray diffraction data, their tetra- and pentanuclear anions [Sb4I16]4− and [Sb5I18]3− have cyclic and linear structure, respectively.

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