Abstract
The results of a unified normal coordinate treatment for vinyl fluoride and the seven deuterated species are presented. Our calculation confirms the out-of-plane assignment of Scherer and Potts. For the in-plane vibrations, we have used a modified valence-force type of potential function and, on the basis of the results, we are presenting a satisfactory assignment for most of the fundamentals. Investigation of the liquid spectra is recommended to resolve the ambiguity of the remaining few undecided in-plane fundamentals.
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