Abstract

AbstractStarting with a quasichemical treatment, simple model calculations are given for the equilibrium composition in surface steps containing A and B kinks, the amount and ratio of which is varied by changing the adjacent gas composition. In connection with deviations from step stoichiometry, the total amount of kinks increases strongly.A nearest neighbour approximation has been applied to the attachment of A or B atoms at kinks from the gas phase, and also from the bulk by formation of vacancies VA or VB. These processes can be formulated separately for the two elements, taking into account the effective formation of bulk atoms of the other kind (BB or BA).

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