Abstract
The model of energy levels crossing in the theory of non-radiative transitions (NRT) has been developed. In the framework of this model NRT are due to the crossing of purely electron energy states of the impurity ion caused by ligands thermal vibrations. Analytical expressions describing the temperature dependence of the NRT probabilities are obtained. The results of calculation of the 3T 2→ 3A 2 NRT for the tetrahedrally coordinated Cr 4+ ion are reported. An accordance between the theoretical calculations and experimental data is discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
