Abstract
AbstractThis paper is a brief survey showing the versatility and unicity of NMR spectroscopy for characterizing the macromolecular architecture in copolymers originated from an emulsion process. Three cases are more particularly described using various NMR techniques i) to carry out high resolution 13 C NMR in order to investigate the microstructure (mainly the monomer sequence distribution as a function of process variables, ii) to perform direct analysis of latex particles by 13 C NMR so as to get insight on the surface morphology of functional particles, iii) to deal with solid‐state NMR on as‐dried particles (or films) in order to obtain quantitative information on the internal morphology of composite latexes.
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