NMR an paramagnetischen Komplexen, XXVIII. 1,1′‐Diisopropylmanganocen, Synthese und paramagnetische 13 C‐und 1 H‐NMR‐Charakterisierung

Abstract

NMR on Paramagnetic Complexes, XXVIII. 1,1′-Diisopropylmanganocene, Synthesis and Paramagnetic 13C and 1H NMR Characterization 1,1′-Diisopropylmanganocene (1), an orange-red liquid, has been synthesized. It yields the first 13C spectrum of a manganocene with shifts up to 1200 ppm. Together with the 1H NMR results this opens a convenient structural determination of manganocenes in solution.