Abstract

Essential additives: The addition of bis(1,3-butadienyl) compounds (tetraenes) was essential in the efficient Ni-catalyzed cross-coupling of organozinc reagents with alkyl bromides and a tosylate (see scheme, X=C(CO2Me)2 or NCH2Ph). The efficiency of the Ni-catalyzed cross-coupling of an alkyl fluoride with a Grignard reagent was also improved by using these tetraenes. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z460246_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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