New Schiff base covalently bonded graphene oxide for removing chromium(VI) from surface runoff

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Hexavalent chromium (Cr(VI)) poses severe health and environmental risk, especially in industrial vicinities where runoff concentrations are elevated by evaporation and sedimentation dynamics. This study investigates the utilization of modified graphene oxide (GO) with abundant active groups as an adsorbent. The novel adsorbent, GO/ATA, was synthesized by covalently attaching a Schiff base (ATA) to GO via a coupling reaction, enhancing its adsorptive properties. The physicochemical properties of GO/ATA were meticulously characterized to ascertain structural and morphological attributes. GO/ATA exhibit exceptional adsorptive capabilities, surpassing the performance parameters of other adsorbents with a maximum of 243.3 mg g−1 at 298 K. The electrostatic attraction between the N-containing functional groups in the graphene oxide and Schiff base composite (GO/ATA) and Cr(VI) is the main mechanism behind the adsorption process; Subsequently, a reduction reaction occurs, facilitated by the thiol and N-containing functional groups in GO/ATA composite, resulting in the transformation of Cr(VI) into Cr(III). This transformation is essential for the following chelation process occurring on the surface of the adsorbent material. Evaluations of recyclability indicated that GO/ATA retains substantial adsorption efficacy, with a reduction from 91.2% to 72.7% over five cycles, thus affirming its recyclability and practical application in the remediation of Cr(VI)-contaminated waterborne environment. Additionally, GO/ATA's effectiveness in removing Cr(VI) from surface runoff was specifically tested, emphasizing its economic and environmental viability.