New halo(pseudohalo)cadmates templated by protonatated N-heterocyclic/diamine molecules

Abstract

At ambient temperature, with various mono(di)protonated N-heterocyclic or diamine molecules as the cations, seven new halo(pseudohalo)cadmates [H2(bpee)][Cd(SCN)4] (bpee = 1,2-bis(4-pyridyl)ethene) 1, [H2(bpyp)][CdBr2(SCN)2] (bpyp = 1,2-bis(4-pyridyl)propane) 2, [H2(mbcha)][Cd3Br2(SCN)6] (mbcha = 4,4′-methylenebis(cyclohexylamine)) 3, [(Hdabco)2Cd3(SCN)8] (dabco = 1,4-diazabicyclo[2,2,2]octane) 4, [H2(bp)][Cd(SeCN)4] (bp = 4,4′-bipiperidine) 5 [H2(pdma)][Cd(SeCN)4]·2H2O (pdma = 1,4-phenylenedimethanamine) 6 and [H2(4,4′-dtdpy)][Cd2Br6] (dtdpy = dithioidipyridine) 7 were obtained. X-ray analysis revealed that (i) compound 1 possesses a three-dimensional (3D) supramolecular network structure with the one-dimensional (1D) channels, constructed from the inorganic [Cd(SCN)4]2− chains by weak S⋯S interactions. The H2(bpee)2+ molecules occupy the space of the channels; (ii) with H2(mbcha)2+ as the cation, the anion [Cd3Br2(SCN)6]2− of compound 3 exhibits a 1D ribbon structure, which can be described as a lengthways packing of planar bi-bridged trimers; (iii) compound 4 is the first example of the cation-controlled 3D thiocyanatocadmate with a composition [Cd3(SCN)8]2−; (iv) with H2(4,4′-dtdpy)2+ as the cation, the anion [Cd2Br6]2− of compound 7 also shows a 1D ribbon structure. This ribbon can be described as a transverse stacking of two planar bi-bridged single chains; (v) the ribbons of compounds 3 and 7 can be visualized as a slice of the two dimensional (2D) CdX2 layer; (vi) in compounds 2, 3, 5, 6 and 7, the organic molecules as the linkers extend the inorganic anionic moieties into various 2D supramolecular layer networks.