Abstract
Various new chiral ferrocenyl phosphine-thioethers and thiophosphine-thioethers with planar chirality only have been efficiently synthesized with good overall yields (39–43%) in enantiomerically pure form by a nine-step sequence involving the introduction of the planar chirality by Kagan’s acetal method. These new P,S and S,S ligands have been successfully used in the palladium-catalyzed asymmetric allylic substitution reaction (ee up to 93%).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
