Abstract
Hydrocarbons and amines are formed in good yields by treatment of thioketones and thioamides, respectively, with iron pentacarbonyl and potassium hydroxide (i.e., HFe(CO)/sub 4//sup -/). A different, and useful, desulfurization reaction occurred by the use of dicobalt octacarbonyl, the cobalt tetracarbonyl anion, or cyclopentadienyliron dicarbonyl dimer as reagents. Mechanisms are proposed for several of these reactions.
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