Abstract
Neutron powder diffraction has been essential for understanding the structures of the new high temperature oxide superconductors because of the difficulty in locating oxygen with X-rays in the presence of heavy metals, especially when single crystals are usually not available. This understanding lead to the discovery of new materials. In this paper we will show how it also sheds light on the crystal chemistry of oxide superconductors—the effects of oxidation/reduction, phase separation, pressure etc.
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