Neutron diffraction characterizations of NbC-Ni cemented carbides thermal residual stresses

Abstract

Cemented carbide materials develop very large micro-stresses due to the coefficient of thermal expansion (CTE) mismatch between the metallic carbide phase and the binder phase. While micro-stresses developed in WC-Co cemented carbides have been investigated, there is very little to no information on the micro-stresses developed in NbC-Ni materials.In this study the thermal stresses developed in NbC-Ni materials as a function of the carbide grain size (from 2.5 μm to 12.8 μm) and the binder content (from 8 vol% to 12 vol%) were characterized by neutron diffraction. It was found that the residual stresses decreased with the increase of the binder content and the increase of the carbides grain size. For both binder and carbide phases, stresses were higher for smaller NbC particles, reaching 4 GPa in Ni at the lowest binder content. In general, stresses were higher than the ones measured in WC-Co or WC-Ni composites. This unexpected finding was attributed to the very different shapes presented by the carbide particles; NbC particles are almost spherical, and WC particles are triangular plates with truncated corners. These different shapes create different strain/stress distributions on the microscopic level around the carbide particles.