NanoSIMS analysis and Auger electron spectroscopy of silicate and oxide stardust from the carbonaceous chondrite Acfer 094

Abstract

We have detected 138 presolar silicate, 20 presolar oxide and three presolar complex grains within the carbonaceous chondrite Acfer 094 by NanoSIMS oxygen isotope mapping. These grains were further investigated by scanning electron microscopy (SEM) and Auger electron spectroscopy for morphological and chemical details and their distribution within the meteorite matrix. The three complex grains consist of Al-rich oxides (grossite and hibonite) attached to non-stoichiometric Si-rich silicates. Refractory Al-rich oxides therefore serve as seed nuclei for silicates to condense onto, which is proposed by condensation theory and astronomical observations. However, in the majority of presolar silicates we did not find any indications for large subgrains. Most of the grains (80%) belong to O isotope Group I ( 17O-enriched) and come from 1 to 2.5 M ⊙ asymptotic giant branch (AGB) stars of close-to-solar or slightly lower-than-solar metallicity. About 60% of these grains are irregular in shape; ∼40% display elliptical morphologies together with smooth, platy surfaces. Three grains with large 17O enrichments ( 17O/ 16O > 3 × 10 −3) have highly irregular shapes and are very small (<250 nm); these grains may have formed in binary star systems or around higher mass ( ∼ 3 M ⊙ ) AGB stars. About 10% of the presolar silicates in this study can be assigned to the O isotope Group IV, which most likely originate from type II supernovae (SNeII). These grains are also generally smaller than 300 nm and are often irregular in shape (88%), consistent with the SNII origin scenario. The presolar grains are generally evenly distributed within the matrix on an mm scale, although in one case a statistically significant clustering of five grains in one 10 × 10 μm 2 sized field is observed. This could be an important hint that the distribution of presolar material in the parental molecular cloud was heterogeneous on a very fine scale. The matrix-normalized abundance of silicate stardust in Acfer 094 is 163 ± 14 ppm, which is among the highest abundance of O-rich stardust in primitive meteorites. Oxide stardust comprises 26 ± 6 ppm of the matrix. Auger Nanoprobe measurements of 69 presolar silicates and oxides (30 on a quantitative, 39 on a qualitative basis) indicate that most of the grains are Fe-rich (Mg/(Mg + Fe) of 0.82 and lower), which is either due to non-equilibrium condensation, secondary alteration, or both. (Mg + Fe)/Si ratios of the silicates are mostly non-stoichiometric and scatter around pyroxene-like rather than olivine-like compositions, which is consistent with recent Auger and transmission electron microscopy observations and astrophysical predictions. Mg-rich grains (Mg/(Mg + Fe) > 0.5) more likely exhibit elliptical, smooth surfaces (14 out of 18 grains), which is an indication that these grains have not been strongly altered since their circumstellar condensation. We identified only one grain similar to the “glass with embedded metal and sulfides” (GEMS) with a statistically significant sulfur content (>2–3 at.%). It remains unclear why the typical high-sulfur GEMS grains are only found in interplanetary dust particles, but have not yet been unequivocally identified in primitive meteorites.