Abstract
Controlling the post-growth assembly of nanowires is an important challenge in the development of functional bottom-up devices. Although various methods have been developed for the controlled assembly of nanowires, it is still a challenging issue to align selectively heterogeneous nanowires at desired spatial positions on the substrate. Here we report a size selective deposition and sequential alignment of nanowires by utilizing micrometer scale hydrophilic/hydrophobic patterned substrate. Nanowires dispersed within oil were preferentially deposited only at a water/oil interface onto the hydrophilic patterns. The diameter size of deposited nanowires was strongly limited by the width of hydrophilic patterns, exhibiting the nanoscale size selectivity of nanowires deposited onto micrometer scale hydrophilic patterns. Such size selectivity was due to the nanoscale height variation of a water layer formed onto the micrometer scale hydrophilic patterns. We successfully demonstrated the sequential alignment of different sized nanowires on the same substrate by applying this size selective phenomenon.
Highlights
Controlling the post-growth assembly of nanowires is an important challenge in the development of functional bottom-up devices
Nanowires dispersed within oil were preferentially deposited only at a water/oil interface onto the hydrophilic patterns
It might be possible to exhibit the nanoscale size selectivity of nanowires by utilizing the nanoscale height variation of water layers formed onto the micrometer scale hydrophilic patterns
Summary
Controlling the post-growth assembly of nanowires is an important challenge in the development of functional bottom-up devices. Various methods have been developed for the controlled assembly of nanowires, it is still a challenging issue to align selectively heterogeneous nanowires at desired spatial positions on the substrate. We report a size selective deposition and sequential alignment of nanowires by utilizing micrometer scale hydrophilic/hydrophobic patterned substrate. D esigning the post-growth assembly of nanowires on the substrate offers a fascinating way to explore novel functional nanoscale devices. This is a clear feature of the assembling method, since high temperature processes limit the range of substrate materials employed This assembling technique has a potential to integrate heterogeneous single crystalline nanowires on the same substrate. This study proposes a size selective deposition technique and sequential alignment of nanowires by utilizing micrometer scale hydrophilic/hydrophobic patterned substrate. This nanoscale size selectivity by micrometer scale patterns can be extended to the sequential alignment of different sized nanowires on the same substrate
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