Abstract
Shear-modulated scanning force microscopy (SM-SFM) is introduced as a nanorheological characterization method for the determination of optoelectronic properties of semiconducting polymer thin films (<100 nm). In this letter, the photoluminescence quantum efficiency of poly(p-phenylenevinylene) (PPV) was directly correlated to the glass transition property by SM-SFM. Conformational changes and chain packing were discussed as a function of the conversion temperature of the soluble PPV precursor. Compared to the bulk, very low glass transition temperature values in the range of 65 to 85 °C were found, which imply an increased molecular mobility in thin films of conjugated polymers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
