Nanocrystalline Cellulose-Derived Doped Carbonaceous Material for Rapid Mineralization of Nitrophenols under Visible Light.

Abstract

Nitrophenols (NPs) and related derivatives are industrially important chemicals, used notably to synthesize pharmaceuticals, insecticides, herbicides, and pesticides. However, NPs and their metabolites are highly toxic and mutagenic. They pose a serious threat to human health and ecosystem. Current work was undertaken to develop a suitable visible-light active catalyst for the sustainable and efficient mineralization of NPs in an aqueous environment. Nanocrystalline cellulose (NCs)-based nitrogen-doped titanium dioxide and carbonaceous material (N-TiO2/C) was synthesized by pyrolysis and sol–gel methods using NCs, polydopamine, and TiO2. The synthesized N-TiO2/C was characterized using different analytical techniques. Photocatalytic degradation of NPs under visible light indicated that acidic pH (3) was most suitable for the optimal degradation. 4-NP degradation followed both pseudo-first-order (R2 = 0.9985) and Langmuir–Hinshelwood adsorption kinetic models (adsorption constant, KLH = 1.13 L mg–1). Gas chromatography–mass spectrometry and ion chromatography analysis confirmed the total mineralization of 4-NP into smaller molecular fragments such as acids, alcohols, and nitrates. The total organic carbon showed that 67% of total carbon present in 4-NP was mineralized into CO2 and CO. The catalyst was recycled for five consecutive cycles without losing its catalytic activities. The degradation mechanism of NPs with N-TiO2/C was also explored.