Abstract
Triarylamines are frequently employed as electron donor functional groups in a variety of organic electronic materials. We herein report the synthesis and in-depth characterisation of aza-analogues of fully bridged triarylamines, consisting of 5-, 6- and 7-membered rings. The impact of nitrogen doping and π-extension on the structural, electronic and optical-properties of these contorted heteroaromatic PAHs is thoroughly investigated and paves the way for an improved understanding of the structure-property relationships.
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