Abstract

We synthesize composite systems of multi-wall carbon nanotubes (MWCNTs)/SiO2 by using the sol-gel method. The dielectric properties of the systems with different-concentration MWCNTs are studied. In our MWCNTs/SiO2 inorganic systems, the twin-percolation phenomenon exists when the concentrations of MWCNTs are 5–10% and 15–20%. The permittivity and conductivity have jumping changes. The twin-percolation phenomenon is attributed to the special transfer mechanism of MWCNTs in the system, determined by hopping and migrating electrons. Variations of dielectric properties and conductance of the MWCNTs/SiO2 systems are conformed to the percolation theory. The special percolation phenomenon and electric properties of MWCNTs/SiO2 can help us comprehend the conductivity mechanism of the MWCNTs/SiO2 systems effectively, and promote the development of a high performance function composite system.

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