Abstract

The mutual interference effects of different concentrations of each of the alkali elements and hydrogen, as the chlorides in solution, on the intensity ef the resonance line for four different concentrations of each of the alkali elements have been studied. All concentrations have been expressed in millimoles per litre. The interference effects were greatest on the lowest concentration and least on the greatest concentration of each element. In general, lithium produced the least effect on the other elements, and the other elements had the least effect on lithium. Hydrogen ion, as hydrochloric acid, caused suppression because of the anion effect, with caesium being suppressed the most. Caesium and rubidium caused the greatest enhancement on the other elements. Because of their very low ionisation potentials, the mutual interference effects of rubidium and caesium on each other were found to be very large.

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