Abstract
Abstract The magnetic g factors and the zero field splittings of the 4 A 2, 2 E, 2 T 1 and 2 T 2 states, all derived from the (t 2)3 configuration, are re-examined. In particular the early work of Sugano and Tanabe, and the later, more precise analysis of Macfarlane are compared. The utility of the Hamiltonian applied to a Russell-Saunders multiplet is demonstrated. Some examples of trigonal Cr(III) complexes are used to illustrate outer sphere perturbations as well as limitations in the conventional ligand field model.
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