Multiple origins of anomalous eutectic microstructure in rapidly solidified Mg-Al alloy

Abstract

Mg-33.3 wt.%Al eutectic alloys were fabricated by melt spinning at wheel speeds from 5 to 50 ms−1. SEM and S/TEM analyses showed the formation of anomalous eutectic structures at all wheel speeds. Four distinctive eutectic microstructures were observed, depending on the wheel speed, each with a unique formation mechanism. At low wheel speeds, solute trapping and high interfacial energy resulted in the remelting of primarily grown regular eutectic microstructures and was responsible for the formation of the anomalous eutectic Type A. A coupled-to-decoupled-growth transition occurred at intermediate wheel speeds giving rise to the anomalous eutectic Type B. The decoupled nucleation and growth of the eutectic phases followed by a coupled dendritic growth lead to the formation of flower-like microstructures at anomalous eutectic Type C. At sufficiently high wheel speed, no sign of regular eutectic was found and a unique cellular microstructure of ϒ phase along with inter- or intragranular α phase grains was formed, anomalous eutectic Type D, as a result of the decoupled nucleation and growth of the eutectic phases. The observed microstructures were examined thoroughly, and the correlated formation mechanisms were discussed on the basis of the SEM images and S/TEM and EDS analysis.