Abstract
After Br(3d) inner-shell ionisation of HBr by synchrotron light, the highly excited intermediate state HBr+(3d−1) generally decays by releasing one Auger electron but, sometimes, two electron can also be emitted. By detecting in coincidence all these electrons analyzed in energy thanks to a magnetic bottle time-of-flight electron spectrometer, we have unraveled all the possible Auger decay channels and filtered them according to the Br3dJ,Mjorbital resulting from fine structure and molecular field splitting.
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