Abstract
A partial least-squares multivariate calibration method for the resolution of mixtures of metal ions from the spectra of the complexes produced in a flow injection (FI) system has been developed. The method has been applied to the simultaneous determination of CuII and ZnII with 4-(4′-methyl-2′-thiazolylazo)-2-methylresorcinol. The reagent exhibits a high absorbance and its spectrum strongly overlaps with the spectra of the complexes that it forms with copper and zinc ions. Chemical and FI variables influencing the system have been optimized and the proposed method validated on the determination of Cu and Zn in blood serum and metal alloys.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
