Multi-scale analysis of 3D printable high-strength engineered cementitious composite with carbon and polyethylene fibres: rheology, printability and hydration kinetics in structural components

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Current standards for evaluating the three-dimensional (3D) printability of concrete rely heavily on observational methods, lacking well-defined criteria. In this work, quantitative printability criteria were established by investigating the impact of carbon fibre (CF) volume fraction (0–0.60%) on the rheology, early-age strength and hydration kinetics of 3D printable high-strength engineered cementitious composites, validated through practical printing tests. Key results demonstrate that increasing the CF content to 0.45% significantly enhanced the rheological properties, increasing the static yield stress by 20.89%, the dynamic yield stress by 41.19% and plastic viscosity by 44.35%. Furthermore, the early-age mechanical strength exhibited a substantial five-fold increase with CF content up to 0.60%, achieving a peak strength of 176.03 kPa. This improvement in strength and rheology correlated with accelerated hydration as the CF fraction was increased from 0 to 0.60%, evidenced by a reduction in the termination point of the accelerated reaction phase from 28.4 h to 19.8 h. Practical printing verification confirmed that optimal printability, defined as the ability to exceed 25 layers, occurred within specific rheological and strength thresholds (static yield stress of 800–980 Pa, dynamic yield stress of 200–320 Pa and early-age strength of 30–120 kPa). These findings establish validated quantitative criteria for assessing the 3D printability of concrete.

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  • Smart Materials and Structures
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The issue which is always debated in the magnetorheological (MR) fluid is the dynamic and static yield stress values obtained from a flow curve. To evaluate these, a suitable constitutive equations are required. The aim of this article is to provide suitable rheological models for the prediction of static and dynamic yield stress from a single flow curve under wide shear rate and magnetic field ranges. The proposed model is well suited for isotropic and anisotropic particle-based MR fluids. The parameters, like yield stress, critical shear rate and viscosity at high shear rate obtained from the fit show systematic variation with applied magnetic field strength. These variations in the parameters can be related to the mesostructure formation and its influence on the MR suspension rheological properties. To further confirm the value of the static yield stress derived from the proposed model, the small-strain oscillatory shear flow experiment is carried out and the static yield stress values are obtained. These values agree well with that obtained from the proposed model. Similarly, to evaluate the dynamic yield stress from the flow curve, modified three parameter model applied to soft glassy materials is used. Here, the critical shear rate parameter obtained from the proposed model is used to deduce dynamic yield stress. It is identified that the values obtained are lower than the static yield stress. Furthermore, at low magnetic field, the static and dynamic yield stress follows the relationship defined by the square dependence of the magnetic field strength. The difference between the static and dynamic yield stress values at high field is greater for anisotropic particle based MR fluid than isotropic particle based MR fluid. This reflects the contribution of particle-particle and particle-carrier interaction in the value of the yield stress in anisotropic particle based MR fluid. Thus, the present model provides a clear idea of the dissipation process that occurs in a shear MR fluid.

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A multi-method investigation into rheological properties, hydration, and early-age strength of cement composites with admixtures recovered from inorganic and bio-based waste streams
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A multi-method investigation into rheological properties, hydration, and early-age strength of cement composites with admixtures recovered from inorganic and bio-based waste streams

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Shear Rate-Dependent Rheological Properties of Mine Tailings: Determination of Dynamic and Static Yield Stresses
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Summary Cuttings transport, in connection with drilling fluid rheology, has been extensively studied in the literature. Despite this, contradictory results continue to be reported regarding the effect of yield stress on cuttings transport. This study uses the concepts of static and dynamic yield stresses to investigate the effects of yield stress on cuttings transport. A modified form of an existing rheological function is proposed to model static and dynamic yield stresses while incorporating flow history. Flow equations are based on the mixture approach and are numerically solved using computational fluid dynamics (CFD) methodology. Assuming that the liquid phase is homogenous and drill cuttings are noncolloidal, it is shown that the distinction between static and dynamic yield stresses diminishes as volumetric cuttings concentration increases. The Herschel-Bulkley function predicts infinite viscosity at the limit of zero shear rate and, hence, improved cuttings transport with increasing dynamic yield stress, whereas in line with the majority of experimental studies, the proposed rheological model shows that high dynamic yield stress is detrimental for cuttings transport. Comparing fluids with the same dynamic yield stress, the fluid with a larger difference between static and dynamic yield stresses has better cuttings carrying capacity. However, these results are only valid for simple yield stress fluids in which yield stress is dependent on shear rate only.

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Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation R. T. Bonnecaze, J. F. Brady; Yield stresses in electrorheological fluids. Journal of Rheology 1 January 1992; 36 (1): 73–115. https://doi.org/10.1122/1.550343 Download citation file: Ris (Zotero) Reference Manager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentThe Society of RheologyJournal of Rheology Search Advanced Search |Citation Search

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Yield stress and rheological characteristics of activated sludge in an airlift membrane bioreactor

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