Morphological characterization, hazardous metal contamination, source identification, and health risk assessment of the fine road dust from Dachang mining area, China.

Abstract

Dachang mining area in China is known as "paradise for mineralogists" due to its most reserves of Sn, Sb, Pb, and Zn non-ferrous metal resources; thus, its evaluation for heavy metal assessment and consequent health risk is unavoidable. Sixty road dust samples were collected from study area to explore pollution level, ecological, and health risks from heavy metals and were analyzed by an inductively coupled plasma optical emission spectrometer and atomic fluorescence spectrometer. The results showed that average concentration of all the heavy metals in road dust in both mining and residential areas were remarkable higher than its corresponding background values, the former being more severe, except for Cr and Co. The morphological investigation showed that most of the particles were much less than 100μm illustrating fine part of the road dust samples. Based on integrated pollution indices, Cd, Sb, As, Zn, and Pb were extremely contaminated and exceeded hundred times of the maximum risk value. The health risk assessment revealed substantially higher carcinogenic and non-carcinogenic risks to children and adult. Highest non-carcinogenic risk resulted from arsenic in mining and residential area with HQing of 644.56 and 267.94 respectively (standard HQ ≥ 1) while carcinogenic risk to children (1.94E + 00) which greatly exceeded from the threshold value of (1.0E-4). Sb, Cd, and Pb also posed carcinogenic and non-carcinogenic risk in road dust which is caused by excessive mining activities and heavy vehicle movement in the study area.