Abstract
Gefangen aktiv: Stabile Pd-Cluster zwischen den Schichten von Montmorillonit katalysieren allylische Substitutionen effizient, wobei die koordinativ ungesättigten Pd-Atome die Bildung von π-Allylpalladium-Zwischenstufen ermöglichen (siehe Schema). Der Heterogenkatalysator lässt sich ohne Verlust an Aktivität oder Selektivität wiederverwenden.
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