Abstract
Thermodynamic properties of the liquid Cd–Sb system has been investigated by measuring the molar volume and sound velocity over the whole composition range as a function of temperature. The volume expansion coefficient and the isothermal compressibility have been deduced. These thermodynamic functions for alloys around 50 at.%Cd show very large temperature dependence in a rather small temperature interval adjacent to the liquidus line. Their dependences on temperature and composition conform to cluster formation and rapid structural changes in liquid Cd–Sb alloys.
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