Abstract
The values of density and surface tension for aqueous solution of ionic liquid(IL) 1-butyl-3-methylimidazolium acetate([C4mim][OAc]) with various molalities were measured in the range of 288.15—318.15 K at intervals of 5 K. On the basis of thermodynamics, a semi-empirical model-molar surface Gibbs energy model of the ionic liquid solution that could be used to predict the surface tension or molar volume of solutions was put forward. The predicted values of the surface tension for aqueous [C4mim][OAc] and the corresponding experimental ones were highly correlated and extremely similar. In terms of the concept of the molar Gibbs energy, a new Eotvos equation was obtained and each parameter of the new equation has a clear physical meaning.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
