Angewandte Chemie International Edition | VOL. 62
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Modelling Development in Radical (Co)Polymerization of Multivinyl Monomers

Publication Date Dec 14, 2022

Abstract

Radical polymerization (RP) of multivinyl monomers (MVMs) provides a facile solution for manipulating polymer topology and has received increasing attention due to their industrial and academic significance. Continuous efforts have been made to understand their mechanism, which is the key to regulating materials structure. Modelling techniques have become a powerful tool that can provide detailed information on polymerization kinetics which is inaccessible by experiments. Many publications have reported the combination of experiments and modelling for free radical polymerization (FRP) and reversible-deactivation radical polymerizations (RDRP) of MVMs. Herein, a minireview is presented for the most important modelling techniques and their applications in FRP/RDRP of MVMs. This review hopes to illustrate that the combination of modelling and wet experiments can be a great asset to polymer researchers and inspire new thinking for the future MVMs experiment optimization and product design.

Concepts

Radical Polymerization Multivinyl Monomers Reversible-deactivation Radical Polymerizations Polymerization Of Monomers Wet Experiments Polymerization Kinetics Product Design Modelling Techniques Modelling Experiments Future Product

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