Abstract

In this study, the structure of Mn+2 doped [Mn(acs)2(H2O)4] acesulfame metal complex was investigated by EPR spectroscopy. Transition metal ion complexes have important applications in both science and technology. Some of these complexes are formed using paramagnetic metal ions Mn+2, VO+2, Cu+2, Fe+3, Cr+3 and therefore are analyzed with EPR spectroscopy to provide structural information. The synthetic sweetener acesulfame is widely used in food and medicine and has widely used in cosmetics. The reason for widespread use depends basically on that acesulfame is easily digested and is not deposited in the body. In addition, acesulfame used as ligands in transition metal complexes show thermochromic and solvatochromic properties. In this study, mixed ligand complex Mn(acs)2(H2O)4 was produced and crystallized and examined with EPR spectroscopy. Structure of the complex and behaviors at different temperatures were discussed.

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