Abstract

Activity coefficients at infinite dilution for benzene, cyclohexane, pentane and heptane in mixtures of squalane and dinonyl phthalate at 303 °K have been determined by the extrapolation of measurements made using a vacuum microbalance technique. Partition coefficients for the solutes at infinite dilution in the solvent mixtures have been derived and found to differ by as much as 6% from those calculated from the partition coefficients for the pure single solvents using the Purnell-Andrade equation, whereas those calculated on the basis of the Flory—Huggins solution theory differ from the experimentally derived values by no more than 1 %.

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